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Growth and green defect emission of ZnPbO nanorods by a catalyst-assisted thermal evaporation-oxidation method

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Publication date: 1 April 2015
Source:Journal of Crystal Growth, Volume 415
Author(s): Moges Tsega , Dong-Hau Kuo , F.B. Dejene
Vertically aligned undoped and Pb-doped ZnO (ZnPbO) nanorods have been successfully synthesized by a thermal evaporation-oxidation method with the Fe–based catalysts on sapphire substrate at different temperatures (600–700°C) for 2h. Effects of growth temperature and Pb-doping on the morphology, structure, and optical properties of as deposited nanorods have been investigated. The products at 600–700°C showed a 1D nanorod morphology with an average diameter in the range 450–150nm, and length in the range 3–6μm. Well-aligned, uniform and elongated nanorods were obtained at 700°C. The photoluminescence (PL) spectra showed that undoped ZnO nanorods exhibited a strong and sharp ultraviolet (UV) band edge emission peak at 380nm (3.26eV), whereas Pb-doped ZnO nanorod arrays exhibited a relative weak ultraviolet (UV) emission at 380nm and a strong green emission at 515nm (2.41eV). A mechanism for the nanorod growth and defect emission is proposed.


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