The solid-solution region for the langasite-type Ca3TaGa3Si2O14 crystal as determined by a lever rule

Publication date: 1 April 2015
Source:Journal of Crystal Growth, Volume 415
Author(s): Hengyu Zhao , Satoshi Uda , Kensaku Maeda , Jun Nozawa , Haruhiko Koizumi , Kozo Fujiwara
A lever rule was applied to data concerning the compositions and proportions of secondary phases coexisting with a Ca3TaGa3Si2O14 (CTGS) matrix to determine the boundary compositions of the solid-solution region for CTGS at 1320°C, as a means of ascertaining the solid-solution for the langasite-type phase in the quaternary CaO-Ta2O5-Ga2O3-SiO2 system. The compositions and proportions of secondary phases were assessed by electron probe micro-analysis as well as through back-scattered electron images. The experimental results showed that the narrow solid-solution region for CTGS is located in a Ta-poor, Ga-poor and Si-rich region relative to its stoichiometric composition.