High-quality single crystal growth and magnetic property of Mn4Ta2O9

Publication date: 15 June 2018
Source:Journal of Crystal Growth, Volume 492
Author(s): Yiming Cao, Kun Xu, Ya Yang, Wangfan Yang, Yuanlei Zhang, Yanru Kang, Xijia He, Anmin Zheng, Mian Liu, Shengxian Wei, Zhe Li, Shixun Cao
A large-size single crystal of Mn4Ta2O9 with ∼3.5 mm in diameter and ∼65 mm in length was successfully grown for the first time by a newly designed one-step method based on the optical floating zone technique. Both the clear Laue spots and sharp XRD Bragg reflections suggest the high quality of the single crystal. In Mn4Ta2O9 single crystal, an antiferromagnetic phase transition was observed below Néel temperature 102 K along c axis, which is similar to the isostructural compound Mn4Nb2O9, but differs from the isostructural Co4Nb2O9. Relative dielectric constant at 30 kOe suggests that no magnetoelectric coupling exists in Mn4Ta2O9.