Growth and quality of gallium selenide (GaSe) crystals

Publication date: 15 October 2013
Source:Journal of Crystal Growth, Volume 381
Author(s): Youbao Ni , Haixin Wu , Changbao Huang , Mingsheng Mao , Zhenyou Wang , Xudong Cheng
High quality nonlinear infrared crystal material GaSe was grown using a seed aided Bridgman–Stockbarger method having a size of 24–26mm in diameter and 55–70mm in length. The crystals were characterized using X-ray diffraction, electron energy scattering, transmission spectrophotometry and infrared microscopy. The transmission spectrum showed that the infrared transmission is about 67% in an 8mm thick sample cleaved along (001) face, and mean absorption 0.01–0.08cm⁻¹ in the range 0.9–15μm. It may be suitable for the fabrication of infrared nonlinear optical devices, photoelectric analyzers of polarized light and so on. Crystals grown by this method with the described procedures may also be useful for other similar layered compounds.